Kinetic Study of Propylene Polymerization with TiCl3-Al2Et3Cl3-n-Bu2O Catalyst

Polymerization of Propylene with [t-BuNSiMe2Ind]TiMe2-MAO Catalyst Systems

ansa-Indenylamidodimethyltitanium complex ([t-BuNSiMe2Ind]TiMe2: 1) was synthesized by one-pot reactions starting from the ligand, MeLi and TiCl4. The structure of 1 was determined by X-ray crystallography and the results obtained revealed that the indenyl ligand coordinate to titanium in an η-tendency. Propylene polymerization was conducted with 1 in toluene or heptane as solvent at 0 ̊C in th...

Ziegler-Natta catalysts for propylene polymerization – Interaction of an external donor with the catalyst

The interaction of the external donor (propyltrimethoxysilane - PTMS) with titanium-magnesium catalysts (TMCs) containing dibutylphthalate (DBP) as internal donor, which were prepared in different ways, was studied by chemical analysis and infrared diffuse reflectance spectroscopy (DRIFTS). The chemical composition of the catalysts after their interaction with heptane solutions of PTMS, PTMS/Al...

Kinetic Study of Methanol to Propylene Process on High Silica H-ZSM5 Catalyst

effective parameters in the design of a loop reactor for bulk propylene polymerization with z-n catalyst

the steps taken in designing a loop reactor for bulk propylene polymerization are discussed. the roles played by several parameters like particle growth factor, catalyst activity and solid fraction on reactor volume at different operating conditions are investigated. at first, based on a fixed production capacity and specific rate of catalyst, reactor volume is determined. next, the length and ...

Determination of kinetic parameters for ethylene polymerization (with and without hydrogen) by Ziegler-Natta catalyst.

In this study, slurry polymerization kinetics of ethylene with TiCl4/Mg(OEt)2/AlR3 Ziegler-Natta catalysts in various conditions using the model of sum square error (SSE) (method I) and model of least square error (LSE) (Method II) was investigated. For this purpose the molecular weight distributions of the samples were deconvoluted to the minimum number of Flor...